全文获取类型
收费全文 | 25081篇 |
免费 | 3405篇 |
国内免费 | 814篇 |
专业分类
电工技术 | 633篇 |
技术理论 | 1篇 |
综合类 | 1264篇 |
化学工业 | 6947篇 |
金属工艺 | 3827篇 |
机械仪表 | 752篇 |
建筑科学 | 609篇 |
矿业工程 | 1557篇 |
能源动力 | 1002篇 |
轻工业 | 1162篇 |
水利工程 | 106篇 |
石油天然气 | 385篇 |
武器工业 | 52篇 |
无线电 | 1490篇 |
一般工业技术 | 5430篇 |
冶金工业 | 3686篇 |
原子能技术 | 152篇 |
自动化技术 | 245篇 |
出版年
2024年 | 70篇 |
2023年 | 523篇 |
2022年 | 591篇 |
2021年 | 1103篇 |
2020年 | 1101篇 |
2019年 | 1008篇 |
2018年 | 1038篇 |
2017年 | 1129篇 |
2016年 | 1287篇 |
2015年 | 1213篇 |
2014年 | 1710篇 |
2013年 | 1922篇 |
2012年 | 1793篇 |
2011年 | 1995篇 |
2010年 | 1404篇 |
2009年 | 1347篇 |
2008年 | 1155篇 |
2007年 | 1320篇 |
2006年 | 1256篇 |
2005年 | 1017篇 |
2004年 | 800篇 |
2003年 | 700篇 |
2002年 | 643篇 |
2001年 | 541篇 |
2000年 | 459篇 |
1999年 | 348篇 |
1998年 | 300篇 |
1997年 | 255篇 |
1996年 | 234篇 |
1995年 | 219篇 |
1994年 | 181篇 |
1993年 | 118篇 |
1992年 | 119篇 |
1991年 | 74篇 |
1990年 | 78篇 |
1989年 | 64篇 |
1988年 | 51篇 |
1987年 | 23篇 |
1986年 | 17篇 |
1985年 | 20篇 |
1984年 | 17篇 |
1983年 | 5篇 |
1982年 | 16篇 |
1981年 | 11篇 |
1980年 | 5篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1974年 | 3篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
11.
《International Journal of Hydrogen Energy》2022,47(10):6638-6649
Developing low cost, highly efficient, and long-term stability electrocatalysts are critical for direct oxidation methanol fuel cell. Despite huge efforts, designing low-cost electrocatalysts with high activity and long-term durability remains a significant technical challenge. Here, we prepared a new kind of platinum-nickel catalyst supported on silane-modified graphene oxide (NH2-rGO) by a two-step method at room temperature. Powder X-ray diffraction, UV–vis spectroscopy, Raman, FTIR spectroscopy and X-ray photoelectron spectroscopy results confirm that GO was successfully modified with 3-aminopropyltriethoxysilane (APTES), which helps to uniformly disperse PtNi nanoparticles. Cyclic voltammetry, chronoamperometry, CO-stripping and rotating disk electrode (RDE) results imply that PtNi/NH2-rGO catalyst has significantly higher catalytic activity, enhance the CO toxicity resistance, higher stability and much faster kinetics of methanol oxidation than commercial Pt/C under alkaline conditions. 相似文献
12.
《International Journal of Hydrogen Energy》2022,47(42):18412-18423
Hydrogen adsorption performance and mechanism upon cycling of the upscaled Ni-doped hierarchical carbon scaffold (HCS) are investigated. Upon 22 hydrogen ad/desorption cycles (T = 25–50 °C and p (H2) = 1–50 bar), the upscaled Ni-doped HCS shows excellent cycling stability with gravimetric capacity of up to 1.51 wt % H2. This is due to mechanical stability of HCS and good distribution of Ni nanoparticles. Hydrogen adsorption mechanism of Ni-doped HCS upon cycling is experimentally and theoretically characterized. Besides dissociative adsorption onto the surface, hydrogen diffusion into the lattice structure of Ni is observed. The latter enhances with the number of ad/desorption cycles and alters the electron sharing mechanisms between Ni and H during adsorption. 相似文献
13.
《International Journal of Hydrogen Energy》2022,47(68):29413-29429
The present study aims to utilize the high surface area of the nanotube structure of halloysite (HNTs), an aluminosilicate clay, and conductivity of reduced graphene oxide (rGO) as support material for the deposition of nickel (Ni) and cobalt (Co) nanoparticles. With that aim, a novel bimetallic cathode electrocatalyst, Co–Ni @ HNTs-rGO (Catalyst H3), is developed. This catalyst is characterized by X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and Transmission Electron Microscopy (TEM). Catalyst H3 demonstrates outstanding oxygen reduction reaction (ORR) activity, electrochemical stability, electrocatalytic performance, and lowest resistance in comparison to the other developed catalysts and conventional Pt/C. Catalyst H3 is used in single-chambered MFCs (microbial fuel cells), where the anode is filled with molasses-laden wastewater. The attained maximum power density in MFC (catalyst H3) is 455 ± 9 mW/m2, which is higher than other catalysts. All the results indicate towards its potential use in MFC application. 相似文献
14.
15.
《International Journal of Hydrogen Energy》2022,47(16):9566-9578
The construction of heterostructure is an effective strategy to synergetically couple wide-band-gap with the narrow-band-gap semiconductor with a mediate optical property and charge transfer capability. Herein, the Z-Scheme CdS/ZnSnO3 (CdS/ZSO) heterostructures were constructed by anchoring CdS nanoparticles on the surface of double-shell hollow cubic ZnSnO3 via the hydrothermal method. The direct recombination of excited electrons in the conduction band (CB) of ZSO and holes in the valence band (VB) of CdS via d-p conjugation at the interface greatly accelerated the internal electric field (IEF). The transfer mode follows the Z-Scheme mechanism, where CdS/ZSO synergistically facilitates the efficient charges transfer from CdS to ZnSnO3 through the intimate interface. Here, ZnSnO3 and CdS serve as an oxidation photocatalyst (OP) and reduction photocatalyst (RP), respectively. Thus, it can promote synergistically the oxidation half-reaction and reduction half-reaction of H2 evolution. The density-functional theory (DFT) calculation further confirms the charges transfer from CdS to ZnSnO3. The hydrogen evolution of 5% CdS/ZSO heterostructure reached 1167.3 μmol g?1, which was about 8 and 3 folds high compared to pristine ZSO (141.9 μmol g?1) and CdS (315.5 μmol g?1), during 3 h of reaction respectively. Furthermore, the CdS/ZSO heterostructures could suppress the photo corrosion of CdS, resulting in its high stability. This work is expected to enlighten the rational design of heterostructure for OP and RP to promote the hybrid heterostructures photocatalytic H2 evolution. 相似文献
16.
《International Journal of Hydrogen Energy》2022,47(22):11500-11510
Herein, a novel ZnTe-based photocatalyst is successfully synthesized via a facile combination of water-bath and hydrothermal processes. Morphology characterization and X-ray diffraction analysis reveal that ZnTe presents irregular granular shape and cubic crystal structure. Moreover, Mott-Schottky measurement shows that the conduction band potential of ZnTe is ?0.84 V (vs NHE). With Eosin Y (EY) sensitization, ZnTe exhibits superior photocatalytic hydrogen evolution activity (223.5 μmol g?1 h?1). Meanwhile, WC-ZnTe heterojunction is constructed by depositing ZnTe nanoparticles on bulk WC and obtains the optimal H2 generation rate (559.1 μmol g?1 h?1) under EY sensitization. Electrochemical and photoluminescence results further prove that WC as electron bridge could reduce the interfacial resistance and suppress e?-h+ pairs recombination. This study explores the potential application of ZnTe as a newly active photocatalyst in photocatalytic water splitting, and emphasizes the synergistic effect of dye sensitization and bridge engineering. 相似文献
17.
为明确大豆蛋白纳米纤维的结构形成和扩宽铁强化剂的食品工业应用,以大豆分离蛋白(soy protein isolate,SPI)为原料,通过5 h的酸热处理制备纳米纤维(soy protein isolate fibrils,Fib SPI),系统研究纤维形成前后蛋白结构的变化,并进一步制备铁纳米颗粒(iron nanoparticles,Fe NPs),探究Fib SPI对铁的稳态化作用。研究结果表明:在酸热处理过程中,SPI产生大量的β-折叠结构,其与硫磺素T结合,显示出增强的荧光强度;此外,7S组分先发生降解,利于纤维成核形成,随后11S逐渐被水解,促进纤维生长;同时水解产生大量的小肽组分,提高了产物的还原力。研究进一步利用Fib SPI递送铁纳米颗粒(Fe NPs),发现与原始SPI相比,铁纳米颗粒可在Fib SPI原位形成胶体稳定的铁-大豆蛋白纳米纤维复合物(Fe FibSPI),并以Fe(II)形式存在,其对乳液体系色泽及稳定性的影响较硫酸亚铁或氯化铁小。该研究可为构建新型植物基铁强化剂递送体系提供理论和方法指导。 相似文献
18.
Suzuki-Miyaura (S-M) is regarded the most powerful way for synthesis biaryls, triaryls, or incorporating of substituted aryl moieties in organic preparation by the cross-coupling of aryl boronic acid with aryl halides using the Pd catalyst. This work reports the combining of the hydrothermal and microwave-assisted protocol to convert the glucose to magnetic carbon spheres (Fe3O4-CSPs) decorated with Pd nanoparticles (NPs) as the catalyst for Suzuki-Miyaura cross-coupling reactions. The physicochemical properties in the produced composite were examined using FESEM, HRTEM, nitrogen isotherms, Raman spectroscopy, FTIR, XPS, and XRD. The as-fabricated composite Pd/Fe3O4-CSPs is mostly spherical with a core–shell structure and possesses a great surface area of 253.2 m2·g-1. Its catalytic performance demonstrates that the composite has excellent stability and high tolerance Suzuki-Miyaura cross-coupling reactions in 30 min at 80 ℃. Both activated and deactivated aryl halides provided excellent yield. The as-fabricated catalyst was recycled for up to four catalytic cycles without a substantial decline in performance. Moreover, this research offers a facile roadmap for synthesizing Pd/Fe3O4-CSPs composites and promoting the practical implementation of Pd/Fe3O4-CSPs catalysts for organic transformation processes. 相似文献
19.
《Advanced Powder Technology》2022,33(8):103663
In this work, a new type of FeSi/FeNi soft magnetic powder core (SMPC) was successfully fabricated by coating FeNi nanoparticles on the surface of FeSi micrometer powder. The effects of different contents of FeNi nanoparticles on the micromorphology, internal structures, and soft magnetic properties of SMPCs were studied. The results show that FeNi nanoparticles adhere to the surface of FeSi powder, which can effectively fill the air gap between FeSi powder and is beneficial to the compaction of the powder cores during the pressing process. Thus, the density of the SMPCs is increased. Compared to FeSi SMPCs, the comprehensive soft magnetic properties of FeSi/FeNi SMPCs have been greatly improved. When adding 15 wt% FeNi nanoparticles, the SMPCs exhibit excellent magnetic properties with high effective permeability (increased by 43.8 %) and low core loss (decreased by 22.1 %). The high performance FeSi/FeNi SMPCs prepared in this work are expected to be widely used in power choke coils, uninterruptible power supplies, and boosts and inverter inductors. 相似文献
20.
《International Journal of Hydrogen Energy》2022,47(80):33919-33937
Development of efficient, low cost and multifunctional electrocatalysts for water splitting to harvest hydrogen fuels is a challenging task, but the combination of carbon materials with transition metal-based compounds is providing a unique and attractive strategy. Herein, composite systems based on cobalt ferrite oxide-reduced graphene oxide (Co2FeO4) @(rGO) using simultaneous hydrothermal and chemical reduction methods have been prepared. The proposed study eliminates one step associated with the conversion of GO into rGO as it uses direct GO during the synthesis of cobalt ferrite oxide, consequently rGO based hybrid system is achieved in-situ significantly, the optimized Co2FeO4@rGO composite has revealed an outstanding multifunctional applications related to both oxygen evolution reaction (OER) and hydrogen counterpart (HER). Various metal oxidation states and oxygen vacancies at the surface of Co2FeO4@rGO composites guided the multifunctional surface properties. The optimized Co2FeO4@rGO composite presents excellent multifunctional properties with onset potential of 0.60 V for ORR, an overpotential of 240 mV at a 20 mAcm?2 for OER and 320 mV at a 10 mAcm?2 for HER respectively. Results revealed that these multifunctional properties of the optimized Co2FeO4@ rGO composite are associated with high electrical conductivity, high density of active sites, crystal defects, oxygen vacancies, and favorable electronic structure arisinng from the substitution of Fe for Co atoms in binary spinel oxide phase. These surface features synergistically uplifted the electrocatalytic properties of Co2FeO4@rGO composites. The multifunctional properties of the Co2FeO4@ rGO composite could be of high interest for its use in a wide range of applications in sustainable and renewable energy fields. 相似文献